(+)-BIS((R)-1-PHENYLETHYL)AMINE 99% (99+% EE/GLC) (C005B-026459)

Application

(+)-Bis[(R)-1-phenylethyl]amine can be used:

• In the synthesis of β-amino acids.
• In the preparation of chiral C(19)-C(26) and C(27)-C(32) moieties of scytophycin C.
• To induce enantioselectivity in the deprotonation of prochiral ketones.
• As a starting material for the synthesis of chiral phenolate ligands through Mannich condensation reaction.
• In the synthesis of chiral phosphoramidite ligands.
• To prepare chiral cyclic isoimidium salts, which are further used to synthesize chiral lactones through Diels-Alder reaction.

Molecular Weight: 225.33. Empirical Formula: C₁₆H₁₉N. linearFormula: [C₆H₅CH(CH₃)]₂NH. Quality Level: 100. Assay: 99%. optical activity: [α. ]20/D +199.0°, neat. optical purity: ee: ≥. 99% (GLC). refractive index: n20/D 1.5523 (lit.). bp: 86 . °C/0.05 . mmHg (lit.). density: 0.985 . g/mL . at 25 . °C (lit.). SMILES string: C[C@@H](N[C@H](C)c1ccccc1)c2ccccc2. InChI: 1S/C16H19N/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16/h3-14,17H,1-2H3/t13-,14-/m1/s1. InChI key: NXLACVVNHYIYJN-ZIAGYGMSSA-N. Pictograms: GHS07. Signal Word: Warning. Hazard Statements: H315 - H319 - H335. Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338. Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3. Target Organs: Respiratory system. Storage Class Code: 10 - Combustible liquids. WGK: WGK 3. Flash Point(F): 235.4 °F - closed cup. Flash Point(C): > 113 °C - closed cup. Personal Protective Equipment: Eyeshields, Gloves, type ABEK (EN14387) respirator filter.