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benzyloxyacetone

BENZYLOXYACETONE 90%

Catalog No.
C005B-026141
Manufacturer No.
489174-5G
Manufacturer Name
Sigma-Aldrich
Quantity
5
Unit of Measure
GR

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Benzyloxyacetone (α-Benzyloxyacetone) is an α-substituted acetone. It undergoes direct aldol reaction with 4-nitrobenzaldehyde in the presence of ( S )-BINAM-L-prolinamide/benzoic acid to form predominantly the syn -diasteroisomer.

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General description

Benzyloxyacetone (α-Benzyloxyacetone) is an α-substituted acetone. It undergoes direct aldol reaction with 4-nitrobenzaldehyde in the presence of (S)-BINAM-L-prolinamide/benzoic acid to form predominantly the syn-diasteroisomer.

Application

Benzyloxyacetone (1-Benzyloxy-2-propanone) may be used in the synthesis of:

  • 7-benzyloxy-6-methyl-5-hepten-1-yne
  • (Z)-2-methylhept-2-en-6-yn-1-o1
  • (S)-(+)-1,2-propanediol, 1-benzyl ether
It may be used as a starting material in synthesizing (2S,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane and (2R,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane.

Molecular Weight: 164.20. Empirical Formula: C10H12O2. linearFormula: C6H5CH2OCH2COCH3. Assay: 90%. impurities: 3% (benzyloxy)acetic acid, 3% benzyl alcohol. refractive index: n20/D 1.512 (lit.). bp: 259 . °C (lit.). density: 1.04 . g/mL . at 25 . °C (lit.). SMILES string: CC(: O)COCc1ccccc1. InChI: 1S/C10H12O2/c1-9(11)7-12-8-10-5-3-2-4-6-10/h2-6H,7-8H2,1H3. InChI key: YHMRKVGUSQWDGZ-UHFFFAOYSA-N. Storage Class Code: 10 - Combustible liquids. WGK: WGK 3. Flash Point(F): 230.0 °F - closed cup. Flash Point(C): 110 °C - closed cup. Personal Protective Equipment: Eyeshields, Gloves, multi-purpose combination respirator cartridge (US).
UPC:
51101912
Condition:
New
HazmatClass:
No
MPN:
489174-5G
CAS:
22539-93-1

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