BENZYLOXYACETALDEHYDE 97% (C005B-051715)

General description

Benzyloxyacetaldehyde is a non-natural aldehyde. It undergoes enantioselective Mukaiyama aldol reaction with silylketene acetal nucleophiles in the presence of C2-symmetric bis(oxazolinyl)pyridine Cu(II) complex (catalyst).

Application

Benzyloxyacetaldehyde may be used in the following syntheses:

• (3S,5S)-methyl 6-benzyloxy-3,5-dihydroxyhexanoate
• (S)-5-benzyloxy-4-hydroxypentan-2-one
• myxothiazols

Benzyloxyacetaldehyde may be used in the synthesis of 1-deoxy-L-xylulose, via antibody catalysis.

Molecular Weight: 150.17. Empirical Formula: C₉H₁₀O₂. linearFormula: C₆H₅CH₂OCH₂CHO. Quality Level: 100. Assay: 97%. form: liquid. contains: 0.5% hydroquinone as stabilizer. refractive index: n20/D 1.518 (lit.). bp: 118-120 . °C/13 . mmHg (lit.). density: 1.069 . g/mL . at 25 . °C (lit.). SMILES string: O: CCOCc1ccccc1. InChI: 1S/C9H10O2/c10-6-7-11-8-9-4-2-1-3-5-9/h1-6H,7-8H2. InChI key: NFNOAHXEQXMCGT-UHFFFAOYSA-N. Pictograms: GHS07,GHS09. Signal Word: Warning. Hazard Statements: H315 - H319 - H335 - H411. Precautionary Statements: P261 - P264 - P271 - P273 - P302 + P352 - P305 + P351 + P338. Hazard Classifications: Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3. Target Organs: Respiratory system. Storage Class Code: 10 - Combustible liquids. WGK: WGK 3. Flash Point(F): 235.4 °F - closed cup. Flash Point(C): 113 °C - closed cup. Personal Protective Equipment: Eyeshields, Gloves, type ABEK (EN14387) respirator filter.