AMMONIUM THIOCYANATE 99.99% METALS BASIS (C005B-022333)

General description

Ammonium thiocyanate is an ammonium salt commonly used for thiocyanation reaction of organic compounds.

Application

Ammonium thiocyanate (ATC) may be used the synthesis of the following:

• Graphitic carbon nitride.
• Three-dimensional nitrogen and sulfur co-doped graphene frameworks (N/S-GFs).
• Substituted 2-aminothiazole derivatives by reacting with α-halo ketone carbonyls in the presence of N-methylimidazole.
• Thiiranes from corresponding oxiranes in the presence of LiBF₄.
• 1,2,4-triazole-3-thiones by a multi-component reaction with benzohydrazide acid and acid chloride in the absence of solvent.

Applied in the formation of novel two-dimensional Cd-SCN coordination solids with unusual and tailorable, checkerboard- or herringbone-patterned structures these structures are important steps toward technologically useful materials.

Features and Benefits

Meets ACS reagent specifications.

Molecular Weight: 76.12. Empirical Formula: CH₄N₂S. linearFormula: NH₄SCN. grade: for inorganic trace analysis. Quality Level: 100. Assay: 99.99% trace metals basis. form: crystals. impurities: ≤. 0.004 . meq/g I₂ consumers, ≤. 0.005% insolubles. ign. residue: ≤. 0.025%. pH: 4.5-6.0. mp: 152-154 . °C (lit.). solubility: water: 76.1 . g/L at . 20 . °C. anion traces: chloride (Cl^-): ≤. 0.005%, sulfate (SO₄^2-): ≤. 0.005%. cation traces: Fe: ≤. 3 . ppm, heavy metals: ≤. 5 . ppm. SMILES string: N.SC#N. InChI: 1S/CHNS.H3N/c2-1-3. /h3H. 1H3. InChI key: SOIFLUNRINLCBN-UHFFFAOYSA-N. Pictograms: GHS05,GHS07. Signal Word: Danger. Hazard Statements: H302 + H312 + H332 - H318 - H412. Precautionary Statements: P273 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1. Supp Hazards: EUH032. Storage Class Code: 13 - Non Combustible Solids. WGK: WGK 1. Flash Point(F): Not applicable. Flash Point(C): Not applicable.