(-)-ALPHA-PINENE 99% (97% EE) (C005B-080006)

Application

(−)-α-Pinene can be used as a precursor for the preparation of:

• Dichloro[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]borane by the in situ reduction and hydroboration reaction.
• α-Pinene oxide by epoxidation using polymer supported by a molybdenum carbonyl catalyst.
• Diisopinocampheylborane (Ipc₂BH), which is used for the asymmetric hydroboration prochiral alkenes.

Molecular Weight: 136.23. Empirical Formula: C₁₀H₁₆. vapor density: 4.7 (vs air). Quality Level: 100. vapor pressure: ~3 mmHg ( 20 °C). Assay: 99%. form: liquid. optical activity: [α. ]20/D −. 50.7°, neat. optical purity: ee: 97% (GLC). autoignition temp.: 491 . °F. refractive index: n20/D 1.465 (lit.). bp: 155-156 . °C (lit.). mp: -64 . °C (lit.). density: 0.855 . g/mL . at 25 . °C. SMILES string: CC1: CCC2CC1C2(C)C. InChI: 1S/C10H16/c1-7-4-5-8-6-9(7)10(8,2)3/h4,8-9H,5-6H2,1-3H3/t8-,9-/m0/s1. InChI key: GRWFGVWFFZKLTI-IUCAKERBSA-N. Pictograms: GHS02,GHS07,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H226 - H302 - H304 - H315 - H317 - H410. Precautionary Statements: P210 - P273 - P280 - P301 + P310 - P303 + P361 + P353 - P331. Hazard Classifications: Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): 88.3 °F. Flash Point(C): 31.3 °C. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter.