ALLYLMAGNESIUM CHLORIDE 2.0M SOLUTION I N TETRAHYDROFURAN (C005B-000158)

General description

Allylmagnesiumchloride solution is an organic compound commonly used as a Grignard reagent inchemical reactions. It is used for the allylation of carbonyl compounds, such as aldehydes and ketones.

Application

Allylmagnesium chloride solution is used as a Grignard reagent in the preparation of:

• Antipsychotic clopixol.
• Polysilane–crown ether polymer (PSEC) using hexachloroplatinic acid as a catalyst.
• 1,7-disubstituted-1,2,3,4-tetrahydroisoquinolinesfrom 3,4-dihydroisoquinoline.

Molecular Weight: 100.83. Empirical Formula: C₃H₅ClMg. linearFormula: CH₂: CHCH₂MgCl. Quality Level: 100. reaction suitability: reaction type: Grignard Reaction. concentration: 2.0 . M in THF. density: 0.995 . g/mL . at 25 . °C. SMILES string: Cl[Mg]CC: C. InChI: 1S/C3H5.ClH.Mg/c1-3-2. . /h3H,1-2H2. 1H. /q. . +1/p-1. InChI key: PLYLAFITHJUEGX-UHFFFAOYSA-M. Pictograms: GHS02,GHS05,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H260 - H314 - H335 - H336 - H351. Precautionary Statements: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338. Hazard Classifications: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 1. Supp Hazards: EUH014 - EUH019. Storage Class Code: 4.3 - Hazardous materials, which set free flammable gases upon contact with water. WGK: WGK 1. Flash Point(F): 1.4 °F - closed cup - Solvent. Flash Point(C): -17 °C - closed cup - Solvent. Personal Protective Equipment: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter.