ALLYLMAGNESIUM BROMIDE 1.0M SOLUTION IN DIETHYL ETHER (C005B-022003)

General description

Allylmagnesium bromide solution serves as a selective nucleophile toward aza-aromatic heterocycles.

Application

Allylmagnesium bromide solution can be used in the Grignard reaction, which is a key step to synthesize:

• 2-(9,10-dihydro-9,10-propanoanthracen-9-yl)-N-methylethanamine (2), a homolog of benzoctamine
• tarchonanthuslactone
• (+)-preussin
• polyhydroxylated quinolizidine alkaloids

Packaging

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Molecular Weight: 145.28. Empirical Formula: C₃H₅BrMg. linearFormula: CH₂: CHCH₂MgBr. Quality Level: 100. reaction suitability: reaction type: Grignard Reaction. concentration: 1.0 . M in diethyl ether. density: 0.851 . g/mL . at 25 . °C. SMILES string: Br[Mg]CC: C. InChI: 1S/C3H5.BrH.Mg/c1-3-2. . /h3H,1-2H2. 1H. /q. . +1/p-1. InChI key: FEMBXICCJNZMMC-UHFFFAOYSA-M. Pictograms: GHS02,GHS05,GHS07. Signal Word: Danger. Hazard Statements: H224 - H260 - H302 - H314 - H336. Precautionary Statements: P210 - P231 + P232 - P233 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P403 + P233. Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1. Target Organs: Central nervous system. Supp Hazards: EUH019. Storage Class Code: 4.3 - Hazardous materials, which set free flammable gases upon contact with water. WGK: WGK 1. Flash Point(F): -40.0 °F - closed cup. Flash Point(C): -40 °C - closed cup. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter.