ALLYL BROMIDE REAGENTPLUS(R) 99% CONTAINS <=1000 PPM PROPYLENE OXIDE AS STABILIZER (C005B-006090)

Application

Allyl bromide can be used as a reagent to prepare:

• Allyl ketones by Barbier-type allylation of various nitriles in the presence of Lewis acid.
• Homoallylic alcohols by reacting with aldehydes or ketones using zinc dust as a catalyst.
• 1,5-hexadiene by reductive C-C bond coupling using silver hydride cluster.

Legal Information

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Molecular Weight: 120.98. Empirical Formula: C₃H₅Br. linearFormula: CH₂: CHCH₂Br. vapor density: 4.2 (vs air). Quality Level: 200. product line: ReagentPlus^®. . Assay: 99%. form: liquid. autoignition temp.: 554 . °F. contains: ≤. 1000 . ppm propylene oxide as stabilizer. expl. lim.: 7.3 . %. refractive index: n20/D 1.469 (lit.). bp: 70-71 . °C (lit.). mp: −. 119 . °C (lit.). density: 1.398 . g/mL . at 25 . °C (lit.). storage temp.: 2-8°C. SMILES string: BrCC: C. InChI: 1S/C3H5Br/c1-2-3-4/h2H,1,3H2. InChI key: BHELZAPQIKSEDF-UHFFFAOYSA-N. Pictograms: GHS02,GHS05,GHS06,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H225 - H301 + H331 - H314 - H340 - H350 - H400. Precautionary Statements: P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): 30.2 °F. Flash Point(C): -1 °C. Personal Protective Equipment: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter.