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6-bromo-2-pyridinecarboxaldehyde (c15-1232-867)

6-BROMO-2-PYRIDINE CARBOXALDEHYDE 97% (C005B-034066)

Catalog No.
C005B-034066
Manufacturer No.
525693-10G
Manufacturer Name
Sigma-Aldrich
Quantity
10
Unit of Measure
GR

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6-Bromo-2-pyridinecarboxaldehyde is a pyridine derivative. It participates in the synthesis of meso -substituted trans -A 2 B 2 -porphyrin.

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General description

6-Bromo-2-pyridinecarboxaldehyde is a pyridine derivative. It participates in the synthesis of meso-substituted trans-A2B2-porphyrin.

Application

6-Bromo-2-pyridinecarboxaldehyde may be used in the synthesis of:

  • 6-([2,2′-bi(1,3-dithiolylidene)]-4-yl)picolinaldehyde
  • tris(2-pyridylmethyl)amine (Tpy) derivative having Tpy core bearing a 3-formyl-phenyl substituent on one of the three arms
  • syn- and anti- forms of 4-(6-bromopyridin-2-yl)-3-methyl-3-phenyloxetan-2-one
  • 6-(2,4,6-triisopropylphenyl)-2-pyridinecarboxaldehyde

Substrate used in a study of a rhodium-catalyzed, reductive aldol coupling with divinyl ketones leading to syn ß-hydroxyenones.

Useful building block for Tris[(pyridyl)methyl]amine ligands.

Molecular Weight: 186.01. Empirical Formula: C6H4BrNO. Quality Level: 100. Assay: 97%. mp: 81-85 . °C (lit.). storage temp.: 2-8°C. SMILES string: [H]C(: O)c1cccc(Br)n1. InChI: 1S/C6H4BrNO/c7-6-3-1-2-5(4-9)8-6/h1-4H. InChI key: QWFHFNGMCPMOCD-UHFFFAOYSA-N. Pictograms: GHS07. Signal Word: Warning. Hazard Statements: H315 - H319 - H335. Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338. Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3. Target Organs: Respiratory system. Storage Class Code: 11 - Combustible Solids. WGK: WGK 3. Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves.
UPC:
12352101
Condition:
New
HazmatClass:
No
MPN:
525693-10G
CAS:
34160-40-2

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