4′-Chloro-2,2′:6′,2′′-terpyridine (C007B-082887)

Product Describtion:4′-Chloro-2,2′:6′,2′′-terpyridine (4′-Cltpy, Cltpy, Cl-terpy) is a tridentate ligand that contains a terpyridine (tpy) site with a Cl site at the 4 -position. It coordinates with various metal ions through these two sites to form different coordination polymers. Crystal structure study shows terpyridine unit of Cltpy adopts a trans, trans conformation. Mol-ecules assemble themselves into stacked columns along the b axis, with an inter-planar distance of 3.51?. It undergoes Williamson type ether reactions with α,ω-bishydroxy-functionalized poly(propylene oxide。 It undergoes Williamson type reaction with α-hydroxy-ω-carboxy-functionalized poly(ethylen-oxide) to afford monoterpyridine terminated telechelics.4′-Chloro-2,2′:6′,2′′-terpyridine may be used in the preparation of the following: mono- and bis-terpyridines bis-hydroxy-functionalized terpyridine cadmium(II) complex and a fullerene derivative 4-functionalized 2,2′:6′,2′′-terpyridines, building blocks for novel supramolecular structures, such as double helicates, dendrimers, micelles and metallo-supramolecular polymersProduct Application:4'-Chloro-2,2':6',2''-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,µ-bishydroxy-functionalized poly(propylene oxide).

Specifications and Purity: ≥98%

MDL Number: MFCD00191930

Molecular Formula: C15H10ClN3

Molecular Weight: 267.71

PubChem CID: 667748

Isomeric SMILES: C1=CC=NC(=C1)C2=CC(=CC(=N2)C3=CC=CC=N3)Cl

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