3-METHYL-2-BUTEN-1-OL 99% (C005B-048615)

General description

3-Methyl-2-buten-1-ol reacts with nitrosocarbonyl benzene to yield 5-hydroxy-isoxazolidines. It is commonly used as fragrance ingredient.

Application

3-Methyl-2-buten-1-ol was used as starting reagent during asymmetric total syntheses of (R)-(+)- and (S)-(-)-umbelactone via Sharpless asymmetric epoxidation reaction.

Molecular Weight: 86.13. Empirical Formula: C₅H₁₀O. linearFormula: (CH₃)₂C: CHCH₂OH. vapor pressure: 1.4 mmHg ( 20 °C). Quality Level: 100. Assay: 99%. form: liquid. expl. lim.: 16.3 . %. refractive index: n20/D 1.443 (lit.). bp: 140 . °C (lit.). density: 0.848 . g/mL . at 25 . °C (lit.). SMILES string: C\C(C): C\CO. InChI: 1S/C5H10O/c1-5(2)3-4-6/h3,6H,4H2,1-2H3. InChI key: ASUAYTHWZCLXAN-UHFFFAOYSA-N. Pictograms: GHS02,GHS05,GHS07. Signal Word: Danger. Hazard Statements: H226 - H302 + H332 - H314 - H335. Precautionary Statements: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3. Target Organs: Respiratory system. Storage Class Code: 3 - Flammable liquids. WGK: WGK 1. Flash Point(F): 124.7 °F - closed cup. Flash Point(C): 51.5 °C - closed cup. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter.