3-BUTENYLMAGNESIUM BROMIDE 0.5M SOLUTIO N IN TETRAHYDROFURAN (C005B-000723)

Application

Synthetic building block that can undergo ring-formation reactions facilitated by ruthenium catalysts.

Used in a key diastereoselective step in the synthesis of (–)-muricatacin from _L-tartaric acid.

Molecular Weight: 159.31. Empirical Formula: C₄H₇BrMg. linearFormula: H₂C: CHCH₂CH₂MgBr. Quality Level: 100. reaction suitability: reaction type: Grignard Reaction. concentration: 0.5 . M in THF. bp: 65 . °C. density: 0.937 . g/mL . at 25 . °C. SMILES string: Br[Mg]CCC: C. InChI: 1S/C4H7.BrH.Mg/c1-3-4-2. . /h3H,1-2,4H2. 1H. /q. . +1/p-1. InChI key: SMLLHQBZPPSOSR-UHFFFAOYSA-M. Pictograms: GHS02,GHS05,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H260 - H302 - H314 - H335 - H336 - H351. Precautionary Statements: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 1. Supp Hazards: EUH018 - EUH019. Storage Class Code: 4.3 - Hazardous materials, which set free flammable gases upon contact with water. WGK: WGK 3. Flash Point(F): -22.0 °F - closed cup. Flash Point(C): -30 °C - closed cup. Personal Protective Equipment: Eyeshields, Faceshields, Gloves.