2-METHYLALLYLMAGNESIUM CHLORIDE 0.5M SOLUTION IN TETRAHYDROFURAN (C005B-000520)

Application

2-Methylallylmagnesium chloride is a general Grignard reagent used in the synthesis of (−)-aplysin, acutumine, dimedol and allyldicyclopentadienyltitanium(III) complexes.

Packaging

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Molecular Weight: 114.86. Empirical Formula: C₄H₇ClMg. linearFormula: H₂C: C(CH₃)CH₂MgCl. reaction suitability: reaction type: Grignard Reaction. Quality Level: 100. concentration: 0.5 . M in THF. bp: 65-67 . °C. density: 0.915 . g/mL . at 25 . °C. SMILES string: CC(: C)C[Mg]Cl. InChI: 1S/C4H7.ClH.Mg/c1-4(2)3. . /h1-2H2,3H3. 1H. /q. . +1/p-1. InChI key: BJVFGWYBOLMUEM-UHFFFAOYSA-M. Pictograms: GHS02,GHS05,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H261 - H302 - H314 - H335 - H351. Precautionary Statements: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235. Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2. Target Organs: Respiratory system. Supp Hazards: EUH014 - EUH019. Storage Class Code: 4.3 - Hazardous materials, which set free flammable gases upon contact with water. WGK: WGK 3. Flash Point(F): -5.8 °F - closed cup. Flash Point(C): -21 °C - closed cup. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter.