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2-cyanobenzylzinc bromide solution

2-CYANOBENZYLZINC BROMIDE 0.5M SOLUTION IN TETRAHYDROFURAN

Catalog No.
C005B-023942
Manufacturer No.
520322-50ML
Manufacturer Name
Sigma-Aldrich
Quantity
50
Unit of Measure
ML

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Application 2-Cyanobenzylzinc bromide can be used as a reactant: In the metal-catalyzed Negishi cross-coupling reactions to prepare aryl or heteroaryl derivatives via carbon-carbon bond formation. To synthesize

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Application

2-Cyanobenzylzinc bromide can be used as a reactant:

  • In the metal-catalyzed Negishi cross-coupling reactions to prepare aryl or heteroaryl derivatives via carbon-carbon bond formation.
  • To synthesize 4-(2-Cyanobenzyl)-3′-(trifluoromethyl)biphenyl by reacting with aryl nonaflate in the presence of Pd(dba)2 as a catalyst.
  • To prepare 2-[(2-cyanophenyl)methyl] benzamide by treating with 2-iodobenzamide using a nickel catalyst.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Molecular Weight: 261.43. Empirical Formula: C8H6BrNZn. linearFormula: NCC6H4CH2ZnBr. Quality Level: 100. concentration: 0.5 . M in THF. density: 0.993 . g/mL . at 25 . °C. storage temp.: 2-8°C. SMILES string: Br[Zn]Cc1ccccc1C#N. InChI: 1S/C8H6N.BrH.Zn/c1-7-4-2-3-5-8(7)6-9. . /h2-5H,1H2. 1H. /q. . +1/p-1. InChI key: LQRNYQAXNZETFP-UHFFFAOYSA-M. Pictograms: GHS02,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H319 - H335 - H336 - H351. Precautionary Statements: P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313. Hazard Classifications: Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2. Supp Hazards: EUH014 - EUH019. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): 1.4 °F - closed cup. Flash Point(C): -17 °C - closed cup.
UPC:
12352115
Condition:
New
HazmatClass:
Yes
MPN:
520322-50ML
CAS:
199465-66-2
Temperature Control Device:
Yes

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