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2'-bromoacetophenone (c15-1223-322)

2'-BROMOACETOPHENONE 99% (C005B-025294)

Catalog No.
C005B-025294
Manufacturer No.
183695-25G
Manufacturer Name
Sigma-Aldrich
Quantity
25
Unit of Measure
GR

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2′-Bromoacetophenone (2-Bromoacetophenone) undergoes enantioselective addition reaction with phenylacetylene catalyzed by chiral camphorsulfonamide . It reacts with aliphatic primary amines in the presence of palladium catalyst to afford

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General description

2′-Bromoacetophenone (2-Bromoacetophenone) undergoes enantioselective addition reaction with phenylacetylene catalyzed by chiral camphorsulfonamide. It reacts with aliphatic primary amines in the presence of palladium catalyst to afford 3-methyleneisoindolin-1-ones.

Application

2′-Bromoacetophenone (2-Bromoacetophenone) was used in the synthesis of novel series of non-condensed 5,5-bicycles.

Molecular Weight: 199.04. Empirical Formula: C8H7BrO. linearFormula: BrC6H4COCH3. Quality Level: 100. Assay: 99%. form: liquid. refractive index: n20/D 1.568 (lit.). density: 1.476 . g/mL . at 25 . °C (lit.). SMILES string: CC(: O)c1ccccc1Br. InChI: 1S/C8H7BrO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3. InChI key: PIMNFNXBTGPCIL-UHFFFAOYSA-N. Storage Class Code: 10 - Combustible liquids. WGK: WGK 3. Flash Point(F): 230.0 °F - closed cup. Flash Point(C): 110 °C - closed cup. Personal Protective Equipment: Eyeshields, Gloves, type ABEK (EN14387) respirator filter.
UPC:
51142501
Condition:
New
HazmatClass:
No
MPN:
183695-25G
CAS:
2142-69-0

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