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(1s,2s)-trans-1,2-cyclohexanediol (c15-1249-826)

(1S 2S)-TRANS-1 2-CYCLOHEXANEDIOL 99% (99% EE/GLC) (C005B-049899)

Catalog No.
C005B-049899
Manufacturer No.
421804-1G
Manufacturer Name
Sigma-Aldrich
Quantity
1
Unit of Measure
GR

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Application (1 S ,2 S )-trans-1,2-Cyclohexanediol may be used in the preparation of (1 S ,2 S )-1,2-cyclohexanediyl bis(4-vinylbenzoate) by reacting with 4-vinylbenzoyl chloride. It may also be used as a chiral ligand for the preparation of

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Application

(1S,2S)-trans-1,2-Cyclohexanediol may be used in the preparation of (1S,2S)-1,2-cyclohexanediyl bis(4-vinylbenzoate) by reacting with 4-vinylbenzoyl chloride. It may also be used as a chiral ligand for the preparation of non-racemic hydroxy phosphonates via titanium alkoxide-catalyzed addition of dimethyl phosphite to the corresponding aldehydes.

C2-symmetric chiral diol with versatile applications as a chiral auxiliary, building block, and chiral ligand.

Molecular Weight: 116.16. Empirical Formula: C6H12O2. linearFormula: C6H10(OH)2. Quality Level: 200. Assay: 99%. optical activity: [α. ]20/D +39°, c :  . 1.6 in H2O. optical purity: ee: 99% (GLC). mp: 107-109 . °C (lit.). SMILES string: O[C@H]1CCCC[C@@H]1O. InChI: 1S/C6H12O2/c7-5-3-1-2-4-6(5)8/h5-8H,1-4H2/t5-,6-/m0/s1. InChI key: PFURGBBHAOXLIO-WDSKDSINSA-N. Pictograms: GHS05,GHS07. Signal Word: Danger. Hazard Statements: H318 - H335. Precautionary Statements: P261 - P280 - P305 + P351 + P338. Hazard Classifications: Eye Dam. 1 - STOT SE 3. Storage Class Code: 11 - Combustible Solids. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable. Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves.
UPC:
51111703
Condition:
New
HazmatClass:
No
MPN:
421804-1G
CAS:
57794-08-8

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