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(1r)-(-)-fenchone

(1R)-(-)-FENCHONE 98+%

Catalog No.
C005B-080065
Manufacturer No.
196436-50G
Manufacturer Name
Sigma-Aldrich
Quantity
50
Unit of Measure
GR

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(1 R )-(-)-Fenchone is a bridged bicyclic ketone found in fennel oil and thuja oil. Application (1 R )-(-)-Fenchone undergoes condensation with pyridinylalkylamines to form chiral iminopyridine ligands, which find applications in enantioselective

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General description

(1R)-(-)-Fenchone is a bridged bicyclic ketone found in fennel oil and thuja oil.

Application

(1R)-(-)-Fenchone undergoes condensation with pyridinylalkylamines to form chiral iminopyridine ligands, which find applications in enantioselective copper-catalyzed Henry (nitro aldol) reaction. It may also be used in the preparation of enantiopure C(7)-anti-substituted fenchones as new chiral sources.

Molecular Weight: 152.23. Empirical Formula: C10H16O. Quality Level: 100. Assay: ≥. 98%. form: liquid. optical activity: [α. ]24/D −. 50.5°, neat. refractive index: n20/D 1.461 (lit.). bp: 192-194 . °C (lit.). mp: 5-6 . °C (lit.). density: 0.948 . g/mL . at 25 . °C (lit.). SMILES string: CC1(C)C2CCC(C)(C2)C1: O. InChI: 1S/C10H16O/c1-9(2)7-4-5-10(3,6-7)8(9)11/h7H,4-6H2,1-3H3/t7-,10+/m0/s1. InChI key: LHXDLQBQYFFVNW-OIBJUYFYSA-N. Pictograms: GHS09. Hazard Statements: H411. Precautionary Statements: P273 - P391 - P501. Hazard Classifications: Aquatic Chronic 2. Storage Class Code: 10 - Combustible liquids. WGK: WGK 2. Flash Point(F): 151.7 °F - closed cup. Flash Point(C): 66.5 °C - closed cup. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter.
UPC:
51142509
Condition:
New
HazmatClass:
No
MPN:
196436-50G
CAS:
7787-20-4

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