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1-tetradecene (c15-1205-267)

1-TETRADECENE >=97.0% GC (C005B-008904)

Catalog No.
C005B-008904
Manufacturer No.
87189-25ML
Manufacturer Name
Sigma-Aldrich
Quantity
25
Unit of Measure
ML

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Application 1-Tetradecene can be used as a reactant to synthesize: 2-Tetradecanone via PdCl 2 /CrO 3 catalyzed oxidation reaction. ( E )-ethyl pentadec-2-enoate, which is used as a key intermediate in the diastereoselective synthesis of

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Application

1-Tetradecene can be used as a reactant to synthesize:

  • 2-Tetradecanone via PdCl2/CrO3 catalyzed oxidation reaction.
  • (E)-ethyl pentadec-2-enoate, which is used as a key intermediate in the diastereoselective synthesis of (+)-nephrosterinic acid and (+)-protolichesterinic acid via Johnson-Claisen rearrangement.

It can also be used as a monomer unit to synthesize high molecular weight polymer [poly(1- tetradecene)] by titanium complex catalyzed polymerization reaction.

Molecular Weight: 196.37. Empirical Formula: C14H28. linearFormula: CH3(CH2)11CH: CH2. vapor density: 6.8 (vs air). Quality Level: 100. Assay: ≥. 97.0% (GC). form: liquid. autoignition temp.: 455 . °F. refractive index: n20/D 1.436 (lit.), n20/D 1.436. bp: 251 . °C (lit.). mp: −. 13-−. 11 . °C (lit.). density: 0.775 . g/mL . at 25 . °C (lit.). SMILES string: CCCCCCCCCCCCC: C. InChI: 1S/C14H28/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3H,1,4-14H2,2H3. InChI key: HFDVRLIODXPAHB-UHFFFAOYSA-N. Pictograms: GHS08. Signal Word: Danger. Hazard Statements: H304. Precautionary Statements: P301 + P310 - P331 - P405 - P501. Hazard Classifications: Asp. Tox. 1. Supp Hazards: EUH066. Storage Class Code: 10 - Combustible liquids. WGK: WGK 3. Flash Point(F): 230.0 °F. Flash Point(C): 110 °C. Personal Protective Equipment: Eyeshields, Gloves, type ABEK (EN14387) respirator filter.
UPC:
12141736
Condition:
New
HazmatClass:
Yes
MPN:
87189-25ML
CAS:
1120-36-1

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