1 2-BIS(DIMETHYLPHOSPHINO)ETHANE 97% (C005B-026798)

General description

1,2-Bis(dimethylphosphino)ethane (dmpe) is a polydentate phosphine ligand. Synthesis of 1,2-bis(dimethylphosphino)ethane has been reported. It reacts with ZrCl₂ to afford ZrCl₄(dmpe)₂ complexes.

Application

1,2-Bis(dimethylphosphino)ethane (dmpe) may be employed as ligand in the preparation of cis-arylmethyl(dmpe) nickel(II) complexes.

Molecular Weight: 150.14. Empirical Formula: C₆H₁₆P₂. linearFormula: (CH₃)₂PCH₂CH₂P(CH₃)₂. Quality Level: 100. Assay: 97%. form: liquid. reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand. refractive index: n20/D 1.507 (lit.). bp: 180 . °C (lit.). density: 0.9 . g/mL . at 25 . °C (lit.). functional group: phosphine. SMILES string: CP(C)CCP(C)C. InChI: 1S/C6H16P2/c1-7(2)5-6-8(3)4/h5-6H2,1-4H3. InChI key: ZKWQSBFSGZJNFP-UHFFFAOYSA-N. Pictograms: GHS02,GHS07. Signal Word: Danger. Hazard Statements: H225 - H315 - H319 - H335. Precautionary Statements: P210 - P302 + P352 - P305 + P351 + P338. Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3. Target Organs: Respiratory system. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter.